Tag Archive: geochemistry


A while back, we started looking at a poorly thought-out article from the website C3Headlines. C3 is starting to make a name for itself as a goldmine of climate comedy- their claims have recently been addressed at Tamino and SkepticalScience.

We’re going to keep digging into C3‘s claim that carbon dioxide concentrations have been increasing linearly over the 20th century. They seemed to draw this claim by eyeballing the graph of CO2 concentrations and qualitatively describing them as linear, apparently using the inset in their first figure to compare linear, quadratic, and exponential trends. This is a faulty method: it’s an elementary fact of calculus that ANY smooth curve, when viewed appropriately, will appear linear. The point has already been made but it’s worthwhile to keep looking because there are some interesting graphical follies at play; examining them further might help us understand how and why graphs are misunderstood.

Figure 1: From C3Headlines’ article on “The Left/Liberal Bizarro Anti-Science Hyperbole”, which claims that CO2 concentrations are increasing linearly. Click to read it, if you dare…

C3‘s second graph in this article measures the change in atmospheric CO2 by calculating a month-to-month percentage change. It’s not entirely clear why they are using a percent change, rather than the standard practice of expressing rate of change as concentration change per year (like the source of their data uses). Whereas ppm/year is an absolute measure, each datum generated by the percentage-change method depends strongly upon the value of the previous month. As a measure of long-term rate of change, it is a bit questionable.

My primary concern, though, is with their use of monthly data in the first place. In my last article, we noted that, without explanation, C3 confined their focus to January CO2 concentrations. Were they consistent, they’d also look at January rates of change – of course, doing so might lead to unacceptable conclusions.

 Figure 2. Rates of CO2 accumulation have been calculated for the month of January, consistent with earlier investigation of January CO2 concentration. Over the period of observation, rates have increased at a significant (P~0.0005) acceleration of 0.11 ppm/year^2. Monthly rates throughout this article have been calculated by considering the change in CO2 between adjacent months, and assuming that a month is 1/12 of a year. Interpolated values of CO2 were used to avoid annoying data holes early in the record.

Instead, they look at the rate of change for every single month on record. Why do I find that problematic? Well, let’s look at the full record, with monthly resolution: Continue reading

I love graphs – my eyes quickly glaze over at a table of numeric data, but a graph, used correctly, can quickly and easily tell the whole story.

‘Used correctly’ is the key phrase – for all their power, graphs are infamously easy to bungle, and when used incorrectly they can misinform – or lie outright.

I’m going to look at an example that touches on a few graphical and statistical concepts near and dear to my heart, as well as carbon geochemistry.

Fig. 1: An image from C3Headlines; the 3 C's are "Climate, Conservative, Consumer". Oh, and the article is titled "The Left/Liberal Bizarro, Anti-Science Hyperbole Continues". It sure would be tragic if they made obvious n00b mistakes after using such language. Click for link!

Coming from an article on the website C3Headlines, this image claims that carbon dioxide concentrations have ‘Linear, Not Exponential Growth’. thereby ‘expos[ing] the lunacy of typical left/liberal/progressive/Democrat anti-science’, The author has reached this conclusion by graphing January CO2 levels* and fitting a linear trendline to them.

Already this is a warning sign – the comparisons the author makes are entirely qualitative, apparently  based up on eyeballing the graph. However, trend lines are created by a statistical process called a linear regression, which comes with a caveat: it will fit a trend line to ANY data given to it, linear or nonlinear. Fortunately, there are also ways of evaluating how good a trend line is. Continue reading

A part of my John Everett series – read more: 0/I – II.0 – II.5 – II.75 –  III.0 – III.3 – IV.0 – IV.4 – IV.8 – V – VII – VIII – Full Report 

We’ve seen that Dr. Everett’s discussion of paleogeochemistry fails to consider both rates of change and the geological record of ocean acidification. There is one last talking point in this section which requires comment:

“From 50-600 million years ago, atmospheric CO2 levels were usually 2-20 times higher than at present. […] This included the age of the dinosaurs, when life was so prolific that we still use its carbon, limestone and chalk.”

Limestone and chalk, like corals and coccoliths, are made out of calcium carbonate. Many deposits of calcium carbonate occurred when there was much more carbon dioxide in the air. The Cretaceous is named after chalk deposits like the White Cliffs of Dover; CO2 levels during the Cretaceous were over 1000 ppm, compared to current levels around 390 ppm. If the ocean deposited calcium carbonate en masse during the high-CO2 Cretaceous, why should we expect it to become hostile to carbonates now?

The chalk cliffs of Dover, massive deposits of calcium carbonate from the high-CO2 Cretaceous. Is this a paradox? Not really. Click for sauce.

The answer lies, again, in time scales.

Over short time scales, like those on which acidification is currently occurring, the saturation state of calcium carbonate is determined by pH, which is controlled by CO2. However, on longer time scales, it’s controlled by another factor. As this article explains:

“Hence, the key, but rather counterintuitive result, is that on long time scales, ocean pH and atmospheric CO2 are decoupled from carbonate mineral saturation state, which is dictated primarily by weathering (in conjunction with the major cation [Ca2+, Mg2+] content of the ocean). Actually, saturation is not entirely decoupled geologically from pH and CO2, as all things being equal, at high CO2 (and a warmer climate), enhanced weathering requires higher carbonate burial and hence higher ocean saturation. Thus, the presence of “carbonate factories” with widespread CaCO3 production and burial is entirely consitent with a high CO2, low pH world. […] Only in significant and geologically “rapid” departures from steady-state carbon cycling will both pH and saturation fall together…” (my emphasis)

In other words, over a long timeline, it’s the calcium that determines calcium carbonate favorability. Over short timelines, it’s the pH- and CO2 emissions are altering the pH on a short timeline.

A part of my John Everett series – read more: 0/I – II.0 – II.5 – II.75 –  III.0 – III.3 – IV.0 – IV.4 – IV.8 – V – VII – VIII – Full Report 

People who minimize or deny the threat of climate change (or ocean acidification, as in part IV of Dr. Everett’s testimony) will often demand that the change be “unprecedented” – that nothing like it has ever happened before in Earth history. (eg, here) The reasoning seems to be that if there have been ecological events like anthropogenic climate change in the past, then current events must not be alarming, since life on earth has each time survived and recovered:

“We know that the Earth has seen these conditions before, and that all the same types of animals and plants of the oceans successfully made it through far more extreme conditions. ” – Everertt (part V)

 

This has always seemed to me like it’s setting the bar a bit low: Do we only become alarmed when faced with the possibility of sterilizing the planet? And considering the amount of violence which earth life has withstood over the ages, it doesn’t seem a very strong statement that human impact is unlikely to wipe it out.

Continue reading

A part of my John Everett series – read more: 0/I – II.0 – II.5 – II.75 –  III.0 – III.3 – IV.0 – IV.4 – IV.8 – V – VII – VIII – Full Report 

Often, in order to explain why a particular Weird Belief is correct despite being at odds with available evidence, the belief holder will invoke conspiracy theories. Young Earth Creationists often invoke a conspiracy by god and/or satan to make the earth look much older than it actually is. Intelligent Design Creationists allege an academic conspiracy to suppress ID research. Climate change skuptiks see conspiracies to falsify data the way I see faces in clouds. It’s not necessarily that conspiracies don’t exist- but because the point of a conspiracy is to mask its own existence, we have to be very careful in deciding which conspiracy theories are justified and which aren’t.

Dr. Everett doesn’t invoke a conspiracy in the classical sense of a bunch of men in suits, smoking cigars in a dimly lit room. But he does seem to invoke a distributed, systemic conspiracy, in which science as a system has been corrupted, and its results can not be trusted. He does this in order to cast doubt on studies of the effects of acidification on calcifiers:

Continue reading

A part of my John Everett series – read more: 0/I – II.0 – II.5 – II.75 –  III.0 – III.3 – IV.0 – IV.4 – IV.8 – V – VII – VIII – Full Report 

The last couple posts looked at Dr. Everett’s discussion of the growth rate of carbon dioxide. There’s one other claim in this section which warrants inspection: that a constant airborne fraction is a challenge to projected acidification.

I got the bright idea to sudo rm -rf in my /etc/ and now GIMP is broken. So none of my sweet graphics this episode. Instead here's a diagram of the carbon cycle, courtesy of NASA (click for sauce.) It's just as well. The coolest thing I could think to draw was some pictures of pie. Mmmm pie.

Here’s what he has to say:

The meaning of this information [the supposed leveling off of CO2 growth rate] (and the future of all climate models[)] became VERY cloudy on 31 December 2009 with the ScienceDaily acknowledgment of a paper published by American Geophysical Union and authored by Wolfgang Knorr that shows “No Rise of Atmospheric Carbon Dioxide Fraction in Past 160 Years”, despite the predictions of carbon cycle/climate models3. The implications of this have yet to be assimilated by the modeling community. This does not mean that CO2 proportion is not rising but rather that the proportion not being assimilated has not changed since 1850. Importantly, it means that the rate of CO2 cycling increases as it becomes more concentrated, and does not decrease as assumed in climate models. The rate of projected growth in CO2 appears to be greatly exaggerated.

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